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WEEE are golden: metal recovery from solvent extraction | Euan Doidge | TEDxUniversityofEdinburgh


[Applause]

Gold is an important metal throughout

history we have adored it this jewelry

and valued it is currency nowadays we

are increasingly relying on it in some

medicines and notably and circuitry in

the contacts of modern electronics and

you can eat gold it even has an e number

but where does gold come from gold is

found naturally in rocks and doors but

only in a few places around the world

around 3000 tons of gold was mined in

2017 with China the US and Australia

being the major contributors even then

gold is found alongside other metals and

in really low concentrations you can

only get up to a gram of gold out for

every ton of rock mind this is a problem

we go to extraordinary lengths to get

the gold to each letter 90% of the

world’s gold comes from mining processes

that reach crushed rocker or with large

quantities of notoriously toxic cyanide

though these processes may allow for the

separation of gold from the rock through

accidental leakages and blatant dumping

of hazardous material cyanide reaches

local water supplies this has a

devastating effect on the local

environment for wildlife and workers in

fact the use of cyanide makes gold the

most toxic metal to produce we also use

incredible amounts of energy and

resources mining and processing tons of

rock to get just a few grams of gold out

to get gold from crushed rock into gold

ring requires many energy intense steps

including physical mining crushing

storing transporting separating refining

and many many more metal production in

general demands 10% of the world’s

energy supply and also produces

significant quantities of carbon dioxide

and other harmful emissions mining

processes in general also produce a lot

of waste and I’d like to give you a

sense of scale of this this is the

superpet gold mine formerly Australia’s

largest opencast gold mine producing 28

tonnes of gold a year

this single mine is one and a half

kilometres wide three and a half

kilometers long

and two and a half kilometers deep this

can be hard to visualize for a single

mind so here’s some perspective you

might be able to make out a single speck

on one of the roads in that pit that’s

actually a dumper truck like this one

that transports crushed rock from one

site to the next how big is that dumper

truck well here’s a worker standing next

to one these mines are vast think of how

much gold we get out of these mountains

compared to how much rock we’ve had to

displace the vast majority of which is

simply disposed of in fact it can take

20 tons of rock to make that one gold

ring this is the severe and detrimental

impact we have on the environment given

our reliance on gold it is important for

us to look to other sources of the metal

and for more efficient metal recovery

processes so we need a better solution

from one tonne of rock you can get up to

a gram of gold but you can get 300 grams

of gold from one tonne of mobile phones

as there’s much more gold in circuitry

than rocks it’s much more efficient and

environmentally friendlier to recycle

gold from waste electrical and

electronic equipment called we instead

of – think of how many phones you’ve had

in your lifetime nothing of what’s

happened to those phones when you got a

new one maybe you gave it to someone

else to use

maybe he threw it in the bin maybe is in

that drawer at home but how many were

recycles in the EU less than 20% of we

is recycled the vast majority of waste

electronics are sent straight to

landfill so you might be thinking well

how much gold is actually in my phone

what’s the point in recycling it the

phones we value so dearly have around 30

milligrams of gold in them are about 85

pence worth this might not seem like a

lot so if I was to gather everyone’s

phone in from this audience of 700

people or so then we’d have 21 grams of

gold are about six hundred and thirty

times worth enough to buy two-thirds of

this might not seem like the best deal

so how about this globally 40 million

tons of weed is sent to landfill every

year this is an urban goldmine in gold

alone this is worth nine billion Pines

if we were to include all the metals and

waste electronics we sent to landfill

this goes up to 22 billion pounds and

this is only set to rise as the sales of

electronic products and therefore amount

of electronic waste is increasing every

year so recycling goes from we really as

a golden opportunity we can minimize our

impacts on the environment by maximizing

the use of metals we already have but we

has many metals in it and gold is not

the most abundant one end there how do I

get gold out of your phone this is where

my research comes in I’m a chemist and I

investigate chemical methods for the

recovery of metals without having to use

toxic reagents I said metals are found

in low concentrations and alongside

other metals so we need some way to

separate and concentrate them one common

way of doing this is to use a technique

called pyro metallurgy which essentially

involves melting the metals out of your

products but this requires a lot of

energy high temperatures and could be

really highly polluting one more

efficient and cleaner way of separating

metals on an industrial scale is to use

a technique called solvent extraction

which has two liquids we can dissolve

all of the metals out of your phone and

into an acidic water solution this gives

us a mixture of metals including iron

and copper platinum and gold which is

the most valuable to recycle the other

liquid is an oil which sits on top of

the water and doesn’t mix into it much

like olive oil sits on balsamic vinegar

I design molecules called extractant

that transport the metal of choice out

of the water and into the oil if we can

do this selectively then we can separate

gold from the mixture this is a sort of

molecular level gold panning

we’re sifting through all the metals in

the mixture and only collecting the one

that we want so how do we get selective

gold separation

every metal in the water has a certain

size likes to form certain shapes has a

certain charge basically has a preferred

chemistry for example gold likes to form

flat squares platinum likes to form

octahedral

I designed molecules that can

discriminate between the metals based on

these features bind to gold and only

gold and transport it into the oil this

selectivity is a bit like the child’s

toy where you can’t get the round peg in

the square hole my molecules are

particularly efficient not only do they

recognize gold squares they transport

multiple at once as molecular at golden

nuggets this gives us more metal outs

from less commercial used we can then

separate off the gold containing oil and

treat it to give us back the gold we

treasure in an overall more efficient

and less damaging process compared to

traditional mining methods this is what

it looks like on the small scale in the

lab we taped your mobile phone and

dissolve it in the acidic water solution

to get what we like to call mobile form

solution for interest the supreme

solution is 10 forms per liter we

contact that mixture of metals with the

colorless oil that contains the

extracted molecules we mix the two

liquids together and as those two

liquids separate we see we see gold move

from the lower mixture up into the oil

achieving saturation we can then

physically separate those two liquids

and treats the oil and a couple of steps

to give us back the gold metal so how

does all of this fit into the bigger

picture what we’re trying to do is help

close the loop and help create what’s

called a circular economy that means

after going through all the effort of

getting our metals in the first place

instead of throwing our products away at

the end of their lives we should be

aiming to recycle as much as possible to

make the most of the metals we already

have to the benefit of the economy the

environment and society know this might

make it look like we’ve solved the

problem we can get gold out of your

phone and busted are many advantages to

recycling metals and gold from we that

are still some challenges we have to

address we need to work with scientists

and engineers to make sure we can deal

with bulk volumes of ever more complex

wastes we need to work with governments

and businesses to make sure we have the

info

structure incentives and framework in

place to be able to collect enough waste

to process it and dismantle it

efficiently because ultimately the value

of what we recover has to be greater

than the cost of recovering it we need

to work together to actively choose to

recycle we so that we can still have

access to metals that don’t cost us the

earth right back at the start I asked

where does gold come from

I’ll repose the question where should

gold come from the answer is we because together we are golden thank you

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